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food products : carboxymethyl cellulose
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Carboxymethyl cellulose, or CMC, is a cellulose derivative with carboxymethyl groups (-CH2-COOH) bound to some of the hydroxyl groups of the glucopyranose monomers that make up the cellulose backbone. Carboxymethylcellulose (CMC; E466) is a derivative of cellulose formed by its reaction with alkali and chloroacetic acid.

 

Structural unit and Molecular structure

The CMC structure is based on the ß-(1-4)-D-glucopyranose polymer of cellulose. Different preparations may have different degrees of substitution, but it is generally in the range 0.6 - 0.95 derivatives per monomer unit.

CMC molecules are most extended (rod-like) at low concentrations but at higher concentrations the molecules overlap and coil up and then, at high concentrations, entangle to become a thermoreversible gel. Increasing ionic strength and reducing pH both decrease the viscosity as they cause the polymer to become more coiled.

Alkali cellulose + Sodium choroacetate -Carboxymethylcellulose sodium
or expressed as follows:
C6H7O2(OH)3+XNaOHC6H7O2(OH)3·XNaOH
C6H7O2(OH)3·XNaOH+mCH2ClCOONa

C6H7O2(OH)3-m·(OCH3COONa)m·(x-m)NaOH+mNaCl+mH2O

 

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